Sharpless epoxidation examples

 

 

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Z-disubstituted olefins are least reactive and selective. OH. Examples of Sharpless Epoxidation: product. Ti(%) tartarate(%). The Sharpless Epoxidation allows the enantioselective epoxidation of prochiral allylic alcohols. The asymmetric induction is achieved by adding an Sharpless-Katsuki Epoxidation: An Enantioselective Catalytic Reaction. Sharpless epoxidation Examples: Geraniol has a 2.7:2.2:1 selectivity (no ee) withKarl Barry Sharpless. • Born in Philadephia in 1941. • Ph.D from Stanford Sharpless Asymmetric Epoxidation Two examples considered:. An example of this Jacobsen hydrolytic kinetic resolution is the conversion of 164 to 47% of enantiopure diol 166 and 49% of enantiopure epoxide 167, using 0.01 Module No and Title Module-12, Sharpless Asymmetric Epoxidation converts only allyl alcohol to the epoxide as can be seen from the following example. The Sharpless epoxidation is an organic reaction used to steroselectively convert an allylic alcohol to an epoxy alcohol using a titanium isopropoxide

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